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The reaction quotient is a fraction. In the numerator is the product of the chemical species on the right-hand side of the equilibrium arrow, each raised to the power of that species coefficient in the balanced chemical equation. It is called the Qc in this case, because molar concentrations are being used. If this was a gas-phase reaction, gas pressures could be used and it would become a Qp. Remember: products over reactants.

The common units of energy are the joule, J, and the calorie, cal A calorimeter is used to measure the heat released or absorbed during a chemical or physical change Know how a calorimeter works The specific heat capacity is the amount of heat needed to change the temperature of 1 gram of a substance by 1 K, while the molar heat capacity is the heat capacity per mole The heat lost by the system in calorimetry is equal to the heat gained by the surroundings The specific heat (c) of a solid can be calculated by: (csolid msolid Tsolid) = cwater mwater Twater or by g = cm T The First Law of Thermodynamics states that the total energy of the universe is constant (Energy is neither created nor destroyed.

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) The Second Law of Thermodynamics states that all spontaneous processes move in a way that increases the entropy (disorder) of the universe The enthalpy change, H, is equal to the heat lost or gained by the system under constant pressure conditions H values are associated with a specific reaction If that reaction is reversed, the sign of H changes If one has to use a multiplier on the reaction, it must also be applied to the H value The standard enthalpy of formation of a compound, Hf , is the enthalpy change when 1 mol of the substance is formed from its elements and all substances are in their standard states The standard enthalpy of formation of an element in its standard state is zero H rxn = Hf products Hf reactants Know how to apply this equation H rxn is usually negative for a spontaneous reaction.

The first two examples in this chapter were text-oriented, but that doesn't mean XML browsers have to be text-oriented. And in fact we should steer away from that idea, because many people have a bias already built-in about how browsers should work after using the World Wide Web. Our next example will display XML documents entirely as nontext graphics; there's no reason XML documents shouldn't work in such a way, and we'll take a look at that now.

S = S products S reactants Know how to apply this equation S is usually positive for a spontaneous reaction The Gibbs free energy is a thermodynamic quantity that relates the enthalpy and entropy, and is the best indicator for whether or not a reaction is spontaneous If G > 0 the reaction is not spontaneous; if G < 0, the reaction is spontaneous; and if G = 0, the reaction is at equilibrium G = Gf products Gf reactants Know how to apply this equation G = H rxn T S rxn Know how to apply this equation For a system not at equilibrium: G = G + RT ln Q = G + 2303 RT log Q Know how to apply this equation For a system at equilibrium: G = RT ln K = 2303 RT log K.

Know how to apply this equation to calculate equilibrium constants..

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Figure 18-8.

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Perhaps the most well-known example of federated ECM is enterprise search. Some organizations have content in hundreds of repositories. The first step towards getting a handle on that information is simply being able to locate it.

oil shale transportation, and (c) cost and labor effectiveness However, difficulties are in the domain of (a) process control and reliability, (b) environmental and ecological impact before and after the processing, (c) long-term ground water contamination, and (d) process efficiency Sites for in situ processing are put back to normal vegetated areas or to the original forms of the environment as close as possible, upon completion There are several advantages associated with oil shale commercialization and they are (a) worldwide abundance and distribution, (b) surface mining or in situ processing possibilities, (c) source for high-quality crude products, (d) source for aliphatic liquid fuels, and last but by no means least (e) oil shale is a politically less sensitive fossil fuel resource The quality of oil shale can be very simply represented by its oil content in the shale.

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